Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Radical -xh acid – or anhydride – acid halide or salt thereof...
Reexamination Certificate
2000-12-07
2003-06-03
Pak, John (Department: 1616)
Drug, bio-affecting and body treating compositions
Designated organic active ingredient containing
Radical -xh acid, or anhydride, acid halide or salt thereof...
C514S560000, C514S738000, C504S157000
Reexamination Certificate
active
06573298
ABSTRACT:
The invention relates to wood which is impregnated with sorbic acid and/or one or more salts of sorbic acid. Furthermore, the invention relates to a method for protecting wood by treatment with sorbic acid and/or one or more salts of sorbic acid.
BACKGROUND OF THE INVENTION
Wood in a moist environment is susceptible to mold and other fungi. A great number of fungi are able to cause damage in wood. These include various wood-staining fungi which can grow relatively rapidly on fresh wooden surfaces and wooden surfaces exposed to weather. The stains which can be caused, for example by Aureobasidium pullulans, are frequently encountered in the case of untreated wood. They are known under the name “blue stains”. The growth of such fungi can lead not only to impairment of the appearance of wood or articles made therefrom, but there is also the risk that fungi transfer from the wood to other articles or products and that even long-lasting forms of the molds can be given off into the ambient air. The inhalation of such fungi can, with sensitized persons, lead, for example, to asthma attacks.
To protect wood and wooden articles from fungal infection, a number of substances and methods of treatment have been proposed.
For example, wood may be protected by drying it to a low H
2
O content. The growth of fungi is bound to the presence of water, generally to water contents above 20%. If the dried wood is exposed to weather, at relatively high relative humidity, the effect of drying is soon eliminated again, however.
Paints, varnishes and similar coatings also prevent fungi from colonizing the surface of the wood or from penetrating into the wood. The methods are proven in practice, but some of them are labor-intensive or costly or only effective provided that wood or wooden articles do not pass into moist surroundings or the paints or coatings are not damaged. However, during transport and other mechanical stress, this is readily possible, so that the protective action is at least in part lost.
In addition, a large number of substances having fungicidal action are known which are used in practice as wood preservatives. For example, tar oils, organotin compounds, various chlorinated aromatic and aliphatic compounds and other substances which can be used alone or in combination. Many of these substances are distinguished by a pronounced activity against fungi. Their use is generally simple. The wood may be lastingly protected against fungal infection in many cases by impregnation. However, a disadvantage of these substances is that they are also distinguished by a greater or lesser toxicity which can make their use in sensitive areas a problem. This applies in particular to use in the food production sector, if transfer even of only traces to foods or food packaging cannot be reliably excluded. In particular in the case of odor-intensive wood preservatives such as the wood tar oils, there is also the risk that even traces of foods cause odor impairment. In practice, nevertheless, it is constantly being observed that especially wooden pallets on which raw materials are transported and delivered are infected during transport and storage by wood-decomposing fungi which can be carried into stores and production areas with the pallets and can thus develop to form a hygiene problem.
Some preservatives which are used to preserve various foods have already been tested for their applicability for preserving wood, especially in the form of derivatives which are not used as such for food preservation. The water-insoluble zinc salt of sorbic acid has, for example, been described as inactive (Holzforschung 17, 97 (1963)). Studies on the use of the commercially unavailable sodium sorbate on bamboo which, owing to its more solid structure, is not completely comparable with the conifer wood customarily used in Germany and which therefore should be somewhat more readily protected against fungal infection, generally resulted, even after a few days, in infection with fungi and worse results than the dehydroacetic acid tested as an alternative. Only at pH 3.0, which is not customary in practice, was sodium sorbate active in these studies (Hakko Kogaku Zasshi 37, 19 (1959)).
Food preservatives and their derivatives are not used in practice as wood preservatives, since they have hitherto been considered to be insufficiently active. In contrast to the wood preservatives used in industry, the preservatives used in food processing are harmless to health, however, so that the transfer of traces to food packaging would be somewhat more tolerable than with industrial preservatives. In addition, they are odor-neutral, so that no odor impairment of the foods is caused by them. This applies especially to sorbic acid, which is closely related structurally to the fatty acid present in food fats and is broken down in the same manner as the fatty acids in the metabolism of the body.
Surprisingly, it has now been found that sorbic acid and especially its water-soluble salts are thoroughly able to protect wood and wooden articles from wood-damaging fungi for a relatively long period even in moist surroundings. This protective action is also achieved at the higher pH of the wood, although in general reference is made to the fact that sorbic acid and its salts are only active at an acidic pH of the material to be preserved (for example: Handbuch Lebensmittelzusatzstoffe [Food additives manual], section B II-1.2, p. 3, 1997).
DESCRIPTION OF THE INVENTION
The invention therefore relates to wood which is impregnated with sorbic acid and/or one or more salts of sorbic acid.
In addition, the invention relates to a wood preservation method, which comprises treating wood with sorbic acid and/or one or more salts of sorbic acid.
For the purposes of the invention, salts of sorbic acid are in particular the water-soluble salts, preferably the sodium salt, potassium salt and magnesium salt.
The protective action of sorbic acid and its salts is of interest and important in particular for pallets for transporting raw materials for food manufacture. Such pallets are exposed during transport and storage to the most varied conditions, including in some circumstances the pallets themselves to high moisture, if the palleted material remains protected against moisture by an overwrap. Protecting the pallets against fungal infection is therefore not simple. However, it has been found that wood, after treatment with salts of sorbic acid, even in moist surroundings remains free from fungal infection for a relatively long time, in fact under conditions corresponding to more than normal circulation of the pallets. By this means wood and wooden articles, especially wooden pallets, which are to be used in the food production and food processing sector, may be protected against unwanted infection with molds without there being any risk that traces of conventional wood preservatives, which are harmful to health or have adverse odor, transfer to foods or food packaging.
Wood may be protected against fungi by a simple treatment with solutions of the salts of sorbic acid, without special or complex methods of application or impregnation being required which would go beyond the customary methods used in wood treatment. Suitable methods are all those by which the surface of the wood or the wood articles can be evenly wetted with solutions of sorbic acid and/or salts of sorbic acid, that is to say dipping, spraying, coating and other methods. The concentrations of sorbic acid and/or salts of sorbic acid are matched to the intended treatment method. They can be varied in principle within wide limits and are restricted upwards only by the solubility limit, and downwards by the low protective action at insufficient concentrations. Limited protective action can be achieved even at a few percent by weight, in particular if dry wood is used and uptake of the solutions is promoted by relatively long dipping times or the wood is intensively wetted by spraying or coating. Customarily, use is made of solutions of the salts in water, or alcohols, such as branched
Nutrinova Nutrition Specialties & Food Ingredients GmbH
Pak John
ProPat L.L.C.
LandOfFree
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