Method for production of ultra-fine gold particle-immobilized ox

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

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502330, 502343, 502344, 502345, B01J 2352

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active

050513940

ABSTRACT:
An ultra-fine gold particle-immobilized oxide is produced by a method which comprises adding an alkali compound to an aqueous solution containing a gold compound and a water-soluble metal salt thereby giving rise to a coprecipitate in the aqueous solution, separating the coprecipitate from the aqueous solution, and calcining the separated coprecipitate. This method is characterized by allowing the presence of a carboxylic acid or a carboxylate in the aqueous solution from the beginning or after the occurrence of the coprecipitate.

REFERENCES:
patent: 4698324 (1987-10-01), Haruta et al.
patent: 4839327 (1989-06-01), Haruta et al.
patent: 4937219 (1990-06-01), Haruta et al.
Chemistry Express, vol. 3, No. 3, pp. 159-162, 1988, M. Haruta et al., "Preparation and Catalytic Properties of Gold Finely Dispersed on Beryllium Oxide".
Journal of Catalysis, vol. 115, pp. 301-309, 1989, M. Haruta et al., "Gold Catalysts Prepared by Coprecipitation for Low-Temperature Oxidation of Hydrogen and of Carbon Monoxide".
Successful Design of Catalysts, 1988, pp. 33-42, M. Haruta et al., "Fine Structure of Novel Gold Catalysts Prepared by Coprecipitation".
Government Industrial Research Institute of Osaka, AIST, MITI, Jul. 6, 1987, pp. 407-414, M. Haruta, "Ultrafine Gold Particles Immobilized by Coprecipitation with Metal Oxides-Their Fine Structures and Applications to Combustion Catalysts". . .
Chemistry Letters, pp. 405-408, 1987, M. Haruta et al., "Novel Gold Catalysts for the Oxidation of Carbon Monoxide at a Temperature Far Below 0.degree. C.".

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