Method for production of sulfide group-containing thiol compound

Organic compounds -- part of the class 532-570 series – Organic compounds – Sulfur containing

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568 39, 568 41, 568 57, 568 59, 568 67, 560152, C07C31906

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059199857

ABSTRACT:
An object is to provide a method for the production of a sulfide group-containing thiol compound which comprises using a solvent capable of effecting the ring-opening addition reaction of an alkylene sulfide to a thiol compound without inducing the alkylene sulfide to polymerize. A method for the production of a sulfide group-containing thiol compound, which comprises effecting the ring-opening addition reaction of an alkylene sulfide represented by the general formula (1): ##STR1## (wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4, which may be identical or different, stand for a hydrogen atom, an alkyl group of 1 to 10 carbon atoms, or an aromatic group of 6 to 15 carbon atoms) to a thiol compound in a solvent of an amide compound or urea substituent-containing compound.

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Fokin et al., Reaction for Nucleophilic Opening of Thiirane Ring by Thiols, Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 660-662, Mar. 1975.
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Snyder et al., The Synthesis of Mercaptans from Olefin Sulfides, J.A.C.S. 69:2675-2677, 1947.

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