Method for production of silicate interlayer cross-linked smecti

Catalyst – solid sorbent – or support therefor: product or process – Zeolite or clay – including gallium analogs – Including organic component

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502 63, 502 84, B01J 2116, B01J 2012

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active

052140121

ABSTRACT:
An interlayer cross-linked smectite is produced by a method which includes the steps of preparing a smectite suspension containing a dissolved water-soluble macromolecular compound, adding a cationic hydroxide oligomer to the suspension thereby subjecting the exchangeable cation in the smectite to ion exchange, allowing the resultant smectite suspension to stand at a fixed temperature for a fixed time thereby allowing the cationic hydroxide oligomer of the smectite to age, separating a solid smectite from the resultant suspension, and heating the separated solid smectite. The interlayer interval of the produced smectite can be controlled by adjusting the amount of the cationic hydroxide oligomer.

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patent: 4753908 (1988-06-01), Kawase et al.
Clays and Clay Minerals, vol. 27, No. 2, The Clay Minerals Society, 1979, pp. 119-124, S. Yamanaka, et al., "High Surface Area Solids Obtained by Reaction of Montmorillonite with Zirconyl Chloride".
Chemical Reactions in Organic and Inorganic Constrained Systems, 1986, D. Reidel Publishing Company, pp. 151-164, T. J. Pinnavaia, "Pillared Clays: Synthesis and Structural Features".

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