Method for production of phthalic anhydride by vapor-phase oxida

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

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C07D30789

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052295273

ABSTRACT:
The production of phthalic anhydride by the catalytic vapor-phase oxidation of a mixture of ortho-xylene and naphthalene is accomplished advantageously by a method which comprises packing in a reaction vessel, as a former-stage catalyst, a catalyst produced by supporting on an inactive carrier a catalytic substance composed of vanadium oxide and a specific anatase type titanium dioxide, Nb, P, Sb, and at least one component selected from the group consisting of K, Cs, Rb, and Tl as oxide and, as a latter-stage catalyst, a catalyst similar to the former-stage catalyst excepting the amount of the at least one component selected from among K, Cs, Rb, and Tl is in the range between 17 and 63% by weight as an oxide based on the amount of the same component used in the former-stage catalyst, both in specified bed heights feeding to this reaction vessel the mixture of ortho-xylene and naphthalene and a molecular oxygen-containing gas at a temperature in the range between 300.degree. and 450 .degree. C.

REFERENCES:
patent: 4472587 (1984-09-01), Benedetti et al.
patent: 4855458 (1989-08-01), Fuhrmann et al.
patent: 4879387 (1989-11-01), Hara

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