Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1992-07-07
1993-11-23
Killos, Paul J.
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
C07C 5100
Patent
active
052646270
ABSTRACT:
A method for the production of methacrylic acid comprising the steps of simultaneously introducing at least one compound selected from the group consisting of methacrolein and isobutyl aldehyde and a molecular oxygen-containing gas into a heat exchanger type shell-and-tube reaction vessel packed with an oxide catalyst containing molybdenum and phosphorus thereby effecting catalytic vapor-phase oxidation reaction and/or catalytic vapor-phase oxidative dehydrogenation reaction and consequently forming methacrylic acid, which method is characterized by having the empty space in the gas outlet part of said reaction vessel with a solid filler.
REFERENCES:
patent: 4374270 (1983-02-01), Ruszola et al.
patent: 4954650 (1990-09-01), Abe et al.
patent: 5206431 (1993-04-01), Hashiba et al.
Aoki Yukio
Kurimoto Ikuo
Tazaki Hiroyuki
Uhara Hiroyuki
Behr Omri M.
Killos Paul J.
McDonald Matthew J.
Nippon Shokubai Co. , Ltd.
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