Method for production of fluorine-containing aromatic compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568437, 568439, 568440, 570127, 570143, 570147, C07C 1908, C07C 2513, C07C 4752, C07C 47546

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active

060433973

ABSTRACT:
A method for the production of a fluorine-containing aromatic compound is provided which allows the relevant reaction to proceed in a standard reaction vessel such as, for example, a glass vessel at room temperature under an ambient pressure without requiring provision of such special devices as have been necessary heretofore or adoption of harsh reaction conditions. This method comprises causing an aromatic compound (A) having a cyclic skeletal part of 6 to 16 carbon atoms containing a plurality of --C(.dbd.O)X groups, wherein X stands for a hydrogen atom, a halogen atom, or an alkyl group of 1 to 10 carbon atoms, and having the remaining hydrogen atoms unsubstituted or partly or wholly substituted with at least one species of halogen atom to react with a compound (B) represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 independently stand for an alkyl group of 1 to 6 carbon atoms or a phenyl group.

REFERENCES:
patent: 2859245 (1958-11-01), Smith et al.
patent: 3914265 (1975-10-01), Middleton
patent: 3976691 (1976-08-01), Middleton
Markovskii et al., "Application of dialkylaminosulfur trifluorides inteh synthesis of fluoroorganic compounds", Synthesis (SYNTBF); 73; (12); pp. 787-789, XP002085446 Inst. Org. Chem.; Kiev; USSR (1973).
Hasek et al., "The Chemistry of Sulfur Tetrafluoride. II The Fluorination of Organic Carbonyl Compounds", J.Amer.Chem.Soc., 82:543-551 (1960).

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