Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1998-08-25
2000-03-28
Richter, Johann
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
568437, 568439, 568440, 570127, 570143, 570147, C07C 1908, C07C 2513, C07C 4752, C07C 47546
Patent
active
060433973
ABSTRACT:
A method for the production of a fluorine-containing aromatic compound is provided which allows the relevant reaction to proceed in a standard reaction vessel such as, for example, a glass vessel at room temperature under an ambient pressure without requiring provision of such special devices as have been necessary heretofore or adoption of harsh reaction conditions. This method comprises causing an aromatic compound (A) having a cyclic skeletal part of 6 to 16 carbon atoms containing a plurality of --C(.dbd.O)X groups, wherein X stands for a hydrogen atom, a halogen atom, or an alkyl group of 1 to 10 carbon atoms, and having the remaining hydrogen atoms unsubstituted or partly or wholly substituted with at least one species of halogen atom to react with a compound (B) represented by the formula: ##STR1## wherein R.sup.1 and R.sup.2 independently stand for an alkyl group of 1 to 6 carbon atoms or a phenyl group.
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Markovskii et al., "Application of dialkylaminosulfur trifluorides inteh synthesis of fluoroorganic compounds", Synthesis (SYNTBF); 73; (12); pp. 787-789, XP002085446 Inst. Org. Chem.; Kiev; USSR (1973).
Hasek et al., "The Chemistry of Sulfur Tetrafluoride. II The Fluorination of Organic Carbonyl Compounds", J.Amer.Chem.Soc., 82:543-551 (1960).
Asako Yoshinobu
Teshima Seiichi
Nippon Shokubai Co. , Ltd.
Oswecki Jane C.
Richter Johann
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