Method for production of alcohol, ketone, and epoxide by oxidati

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568401, 549523, 549533, C07C 4533

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056230907

ABSTRACT:
An alcohol or a ketone or a mixture thereof is produced from a saturated hydrocarbon or an epoxide is produced from an unsaturated hydrocarbon by passing a mixture comprising of molecular hydrogen, the saturated or unsaturated hydrocarbon and oxygen through a bed of a catalyst comprising a titanium dioxide carrier and ultrafine gold particles deposited on the carrier, thereby effecting the oxidation of the hydrocarbon with oxygen.

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Bull. Chem. Soc. Japan, vol. 64, No. 8, pp. 2513-2518, 1991, Toshihiro Takai, et al., "Aerobic Epoxidation of Olefinic Compounds Catalyzed by Tris(1,3-Diketonato)Iron(III)".
J. Chem. Soc. Chem. Commun., pp. 1446-1447, 1992, T. Tatsumi, et al., "Hydroxylation of Benzene and Hexane by Oxygen and Hydrogen Over Palladium-Containing Titanium Silicalites".
J. Am. Chem. Soc., vol. 109, No. 9, pp. 2387-2389, 1987, Norman Herron, et al., "A Highly Selective Zeolite Catalyst for Hydrocarbon Oxidation. A Completely Inorganic Mimic of the Alkane.omega.-Hydroxylases".
Database WPI, Derwent Publications, AN-94-061881, JP-A-06-016422, Jan. 25, 1994.

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