Method for production of a solid catalyst for olefin...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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C502S125000, C502S134000, C502S154000, C502S156000, C526S124900

Reexamination Certificate

active

06864208

ABSTRACT:
A catalyst solid for olefin polymerization comprisingA) at least one magnesium halide,B) at least one metallocene complex andC) at least one compound capable of forming metallocenium ions,is prepared byi) firstly preparing finely divided support particles consisting of the magnesium halide A) and an C1-C8-alcohol having a mean particle diameter of from 1 to 200 μm from an adduct of the magnesium halide A) and a C1-C8-alcohol, where the adduct contains from 1.5 to 5 mol of the C1-C8-alcohol per mole of magnesium halide,ii) then depositing the compound C) capable of forming metallocenium ions on the finely divided support particles andiii) subsequently bringing the reaction product hereby obtained into contact with the metallocene complex B). This catalyst solid can be used for the polymerization or copolymerization of olefins.

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Wisenfeldt et al., “WVII. Racemic and meso diastereomers of group IV metallocene derivatives with symmetrically substituted, dimethylsilanediyl-bridged ligand frameworks. Crystal structure of R,S- Me2Si(3-t-Bu-5-MeC5H2)2-ZrCI2”J. of Organometallic Chemistry369:359-370 (1989).

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