Method for production of 2-chloropyridine and 2,6-dichloropyridi

Distillation: processes – separatory – With chemical reaction – Including step of adding catalyst or reacting material

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203 95, 203 96, 203DIG16, 20415771, 546345, B01D 334

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active

055363768

ABSTRACT:
A method for producing 2-chloropyridine and 2,6-dichloropyridine by the steps of mixing vaporized chlorine and vaporized water to obtain dilute chlorine; introducing the dilute chlorine and vaporized pyridine into a reactor; and reacting the vaporized pyridine with the dilute chlorine in a gas phase under ultraviolet rays irradiation. By the method, 2-chloropyridine and 2,6-dichloropyridine can be produced in high yields. The present invention is also directed to a method for separating 2,6-dichloropyridine from a mixture containing 2,6-dichloropyridine, 2-chloropyridine and pyridine by the step of carrying out distillation of the mixture containing 2,6-dichloropyridine, 2-chloropyridine and pyridine in the presence of water while adding sulfuric acid to a distillation column. Highly purified 2,6-dichloropyridine can be separated by the method.

REFERENCES:
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patent: 3668209 (1972-06-01), Kyriacou
patent: 3899495 (1975-08-01), Beschke et al.
patent: 3969205 (1976-07-01), Kawamura et al.
patent: 4054499 (1977-10-01), Kawamura et al.
patent: 5141608 (1992-08-01), Kamei

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