Method for producing, via organometallic compounds, organic...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C549S206000, C549S004000

Reexamination Certificate

active

10491966

ABSTRACT:
A method for preparing aryllithium compounds of the formulae (IV) and (VI) includes reacting halogen compounds (I) with lithium metal to obtain a lithium compound of formula (II) and reacting the lithium compound of formula (II) with aromatic compounds of the formulae (III) and/or (V) to form lithium aromatics (IV) and (VI).

REFERENCES:
patent: 3649701 (1972-03-01), Smith
patent: 6448433 (2002-09-01), Marcuccio et al.
patent: 2005/0001333 (2005-01-01), Wehle et al.
patent: WO 0064905 (2000-11-01), None
Gilman et al., “Secondary & Tertiary Alkyllithium Compounds & Some Interconversion Reactions with Them”, J. Amer. Chem. Soc., vol. 63 pp. 2479-2482 (1941).
Bartlett et al. “t-Butyllithium,” J. Amer. Chem. Soc. vol. 63 pp. 3229-3230 (1941).
Tarbell et al., “The Action of Lithium on an Optically Active Aliphatic Chloride,” J. Amer. Chem. Soc. vol. 61 pp. 1203-120-5 (1939).
Schlosser et al., “Organonetallics in Synthesis, A Manual” John Wiley & Sons, Ltd., pp. 223-347 (2002).
PCT ISR for PCT/EP02/11502, Feb. 6, 2003.
English Translation of PCT IPER for PCT/EP02/11502, Apr. 29, 2004□.

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