Method for producing uncrosslinked polyacetylene film

Plastic and nonmetallic article shaping or treating: processes – Gas or vapor deposition of article forming material onto...

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26433117, 427171, 4272556, 427301, B29C 4108, B05D 304

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049275780

ABSTRACT:
Virtually uncrosslinked polyacetylenes in film form are prepared by polymerization of acetylene using a liquid catalyst system consisting of an organicaluminum compound and a titanate in the form of a solution in a viscous inert liquid on a substrate to which the catalyst solution is applied, by a process in which, after the polymerization, the polymer is treated with a strong reducing agent which is inert to the organoaluminum catalyst component, the polymer is, if desired, oriented and is freed from residual catalyst and reducing agent by washing with a liquid, doped with a strong electron acceptor or electron donor in a conventional manner to increase the conductivity and dried, and the materials thus obtained are, if desired, covered with a layer or sheath of nonconductive material.

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patent: 4675137 (1987-06-01), Umetsu
Shirakawa et al., Journal of Polymer Science: Polymer Chemistry Edition, vol. 12, pp. 11-20, 1974.
Naarmann, Die Angewandte Makromolekulare Chemie 109/110 (1982), pp. 295-338.

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