Method for producing the tautomeric form of (1) of...

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

Reexamination Certificate

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C424S401000

Reexamination Certificate

active

07074922

ABSTRACT:
The invention relates to a method for producing the tautomeric form (I) of 2,4,6-trianilino-p-(carbo-2′-ethylhexyl-1′-oxy)-1,3,5-triazine by the crystallization of a tautoner mixture in the presence of one or more solvents selected from the group consisting of aliphatic alcohol having 2 8 C-atoms made of aliphatic alcohol, aliphatic carboxylic acid alkyl esters having a total of between 3–10 C-atoms, aromatic carboxylic acid alkyl esters having a total of between 8–12 C-atoms, aliphatic carboxylic acid esters having a total of between 3 9 C-atoms, carboxylic acid nitriles having a total of between 2–8 C-atoms, dialkylketones having a total of between 3–6 C-atoms and aliphatic sulphones having a total of between 3–6 C-atoms. The solvent or solvent mixture can additionally contain up to 30 wt % of a hydrocarbon (I) acts as a light protecting agent in cosmetic preparations.

REFERENCES:
patent: 4617390 (1986-10-01), Hoppe et al.
patent: 4656272 (1987-04-01), Martin et al.
patent: 35 18670 (1986-11-01), None
patent: 087 098 (1983-08-01), None
patent: 202 611 (1986-11-01), None
Advances in Heterocyclic Chemistry, Supplement 1, The Tautomerism of Heterocycles, Academic Press New York, 1976, Kp 2, S. 168.

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