Method for producing silver salt-containing facilitated...

Coating processes – With post-treatment of coating or coating material – Heating or drying

Reexamination Certificate

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C521S027000, C521S031000, C210S638000, C210S651000, C427S384000, C427S385500

Reexamination Certificate

active

06878409

ABSTRACT:
The present invention relates to polymer membranes for separating olefins from paraffins which have the similar molecular size and close boiling point. More particularly, it relates to a silver salt-containing facilitated transport membrane for olefin separation, and also a method for producing the same. An object of the present invention is to provide a silver salt-containing facilitated transport membrane for olefin separation having improved stability, and also a method for preparing the same, which exhibits no deterioration in membrane performance even when operated for an extended period of time. The facilitated transport membrane for olefin/paraffin separation of the present invention comprises a polymer, a silver salt, and a phthalate compound represented by the following formula (1)wherein R denotes an alkyl group of 2 to 8 carbon atoms or a phenyl group.

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patent: 5236570 (1993-08-01), Ma et al.
patent: 5670051 (1997-09-01), Pinnau et al.
Safarik et al., “Olefin/Paraffin Separations by Reactive Absorption: A Review”, Ind. Eng. Chem. Res. vol. 37, No. 7, pp. 2571-2581 (1998).
Jose et al., Chemical Communications (2001), (20), pp. 2046-2047.
Jose et al., Chemistry of Materials (2002), 14(5), pp. 2134-2139.

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