Method for producing propylene hydroformylation products and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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C562S531000, C562S534000, C568S454000, C568S476000, C568S478000

Reexamination Certificate

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06864391

ABSTRACT:
A process for preparing hydroformylation products of propylene and for preparing acrylic acid and/or acrolein comprises a) feeding a propylene-containing feed in which from 2 to 40% by weight of propane is present and also carbon monoxide and hydrogen into a reaction zone and reacting this mixture in the presence of a hydroformylation catalyst to form hydroformylation products of propane, b) separating a stream consisting essentially of unreacted propylene and propane from the output from the reaction zone, and c) subjecting the stream consisting essentially of propylene and propane to a catalytic gas-phase oxidation in the presence of molecular oxygen to form acrylic acid and/or acrolein.

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Stern et al. Reaction Network and Kinetics of Propane Oxydehydrogenation over Nickel Cobalt Molybdate. Journal of Catalysis, vol. 167 (2), 1997, p 560-569.

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