Method for producing polyisobutylenes

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Treating polymer containing material or treating a solid...

Reexamination Certificate

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C528S492000, C526S237000, C585S525000, C585S823000

Reexamination Certificate

active

06846903

ABSTRACT:
Polyisobutenes are prepared by cationic polymerization of isobutene or isobutene-containing hydrocarbon streams in the liquid phase in the presence of boron trifluoride as a catalyst, the catalytic activity of the boron trifluoride being partially or completely eliminated at a desired time by means of a solid deactivator, by a process in which the solid deactivator has boron trifluoride-binding primary, secondary, tertiary and/or quaternary nitrogen atoms and is insoluble in the reaction mixture.

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H. Guetterbock Polyisobutylen und Isobutylen-Mischpolymerisate, Springer-Verlag, Berlin, pp. 77-104 1959.
Puskas et al J. Polymer Sci.: Symposium No. 56, pp. 191-202 1976.

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