Method for producing polyisobutene

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S209000, C526S212000, C526S237000, C526S348700, C585S521000, C585S525000

Reexamination Certificate

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10542928

ABSTRACT:
A process is described for preparing polyisobutene having a content of terminal vinylidene groups of at least 75 mol % by polymerizing isobutene or isobutenic hydrocarbon mixtures in the liquid phase in the presence of a boron trifluoride complex catalyst of the compositionin-line-formulae description="In-line Formulae" end="lead"?(BF3)a.L1b.L2c.L3din-line-formulae description="In-line Formulae" end="tail"?where L1is water, a primary C1–C5-alkanol and/or a secondary C3–C5-alkanol, L2is at least one aldehyde and/or one ketone, L3is an ether having at least 5 carbon atoms, a secondary alkanol having at least 6 carbon atoms, a primary alkanol having at least 6 carbon atoms and/or a tertiary alkanol, the b:a ratio is in the range from 0.9 to 3.0, the c:a ratio is in the range from 0.01 to 0.5, and the d:a ratio is in the range from 0 to 1.0.

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Research Disclosure Database No. 424060, “Polymerisation Process,” Research Disclosure Journal ISSN 0374-4353, Kenneth Mason Publications Ltd., UK, Aug. 1999 (Anonymous).
English language translation of CN 1323841, published Nov. 28, 2001.

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