Method for producing polyamide-imides from CO, bis-imide and pol

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528 15, 528 25, 528 27, 528 28, 528 33, 528170, 528220, 528225, 528229, 528319, 528321, C08G 7314

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052666794

ABSTRACT:
A method for preparing a polymer including the step of reacting carbon monoxide and a reactant pair having respective general formulas ##STR1## a reactant having the general formula ##STR2## in the presence of catalyst and free iodo or bromo ions. X is --Br or --I. n is an integer from 0 to 4. R.sup.1 is selected from the group consisting of alkyl, arylalkyl, aryl, heteroaryl, and cycloalkyl. R.sup.2 is selected from the group consisting of ##STR3## wherein each R.sup.5 is independently selected from the group consisting of alkyl and aryl, m is an integer from 1-12, and j is an integer between 0 and 300.

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patent: 4933468 (1990-06-01), Perry et al.
Macromolecules "Novel Synthesis of Aromatic Polyamides by Palladium-Catalyzed Polycondensation of Aromatic Dibromides, Aromatic Diamines and Carbon Monoxide" 1988, vol. 21, 1908-1911.
Chemical Communications, J. of the Chemical Soc., W. J. Scott, 1987, 1755.
Chemical Communications, J. of the Chemical Soc., Mutin et al, 1988, 896.

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