Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2000-09-05
2001-09-18
Teskin, Fred (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C526S078000, C526S079000, C526S087000, C526S313000
Reexamination Certificate
active
06291604
ABSTRACT:
BACKGROUND OF THE INVENTION
The present invention relates to a method for producing poly(p-t-butoxystyrene).
More specifically, the present invention relates to a method for producing poly(p-t-butoxystyrene) by a polymerization of p-t-butoxystyrene characterized in that the raw material, the p-t-butoxystyrene or a solution thereof, has a water content in a specific range and is added to a mixture of a reaction solvent and a polymerization initiator.
Poly(p-t-butoxystyrene) is well-known as a raw material of resist used for producing LSI and the like. In recent years, those having narrow molecular weight distribution, particularly those having “weight average molecular weight(Mw)
umber average molecular weight(Mn)” about 1.30 or smaller, more preferably 1.20 or smaller, are desired.
As an example of method for producing poly(p-t-butoxystyrene), JP-A-6-298869 discloses a method in which a solution of p-t-butoxystyrene is added to a mixture of a reaction solvent and a polymerization initiator.
According to this method, however, poly(p-t-butoxystyrene) having narrow molecular weight distribution is not necessarily obtained, and the compound having Mw/Mn exceeding 1.30 is often produced. Therefore, this method has an industrial problem.
On the other hand, as a method for obtaining poly(p-t-butoxystyrene) having narrow molecular weight distribution securely, a method in which a polymerization initiator is added at a stroke to a mixture of a reaction solvent and p-t-butoxystyrene is known(JP-A-8-29983). Although poly(p-t-butoxystyrene) having narrow molecular weight distribution can be obtained according to this method, the addition of polymerization initiator in a very short period causes very rapid proceeding of the exothermic reaction and abrupt heat generation. As a result, the temperature control becomes difficult, and this method also has an industrial problem.
The present inventors have conducted extensive studies to resolve the above problems of the conventional methods, and to develop a method for producing poly(p-t-butoxystyrene) having narrow molecular weight distribution securely not causing abrupt heat generation.
As a result, they have found that, when poly(p-t-butoxystyrene) is produced by a method in which p-t-butoxystyrene or a solution thereof is added to a mixture of a reaction solvent and a polymerization initiator, the molecular weight distribution of poly(p-t-butoxystyrene) is affected by water contained in the raw material, p-t-butoxystyrene or a solution thereof, as an impurity, and that poly(p-t-butoxystyrene) having narrow molecular weight distribution can be produced securely by using a p-t-butoxystyrene having water content in a specific range of 5-70 ppm. Thus, the present invention has been completed.
SUMMARY OF THE INVENTION
The present invention provides a method for producing poly(p-t-butoxystyrene) by a polymerization of p-t-butoxystyrene characterized in that the p-t-butoxystyrene or a solution thereof is added little by little to a mixture of a reaction solvent and a polymerization initiator, and water content in the p-t-butoxystyrene or the solution thereof is in a range of 5-70 ppm.
EMBODIMENT OF THE INVENTION
In the present invention, the polymerization of p-t-butoxystyrene is conducted in a reaction solvent.
Examples of the reaction solvent used include aromatic hydrocarbons such as benzene, toluene and xylene, aliphatic hydrocarbons such as hexane, heptane, cyclohexane and methylcyclohexane, ethers such as tetrahydrofuran, 1, 4-dioxane and ethyleneglycol dimethylether, and mixtures of two or more of them. Among them, a mixed solvent of a hydrocarbon and an ether is preferably used.
Amount of the reaction solvent is usually about 1-20 times by weight, preferably 2-10 times by weight, based on the amount of p-t-butoxystyrene.
In the present invention, a polymerization initiator is used for the polymerization of p-t-butoxystyrene.
As the polymerization initiator, for example, an organic alkali metal compound is used. Examples of the organic alkali metal compounds include organic lithium compounds such as n-butyllithium, sec-butyllithium, i-butyllithium, t-butyllithium, 2-methylbutyllithium and lithiumnaphthalene, and organic sodium compounds such as sodiumnaphthalene, sodiumanthracene, sodium-&agr;-methylstyrenetetramer and sodiumbiphenyl. Among them, n-butyllithium, sec-butyllithium and the like are preferably used.
Amount of the organic alkali metal compounds to be used in the present invention varies based on the intended molecular weight of poly(p-t-butoxystyrene). Usually, the amount is preferably about 10
−5
-10
−3
mole per 1 g of p-t-butoxystyrene monomer.
In the present invention, p-t-butoxystyrene or a solution of p-t-butoxystyrene is added to a mixture of a reaction solvent such as that mentioned above and a polymerization initiator such as that mentioned above.
Examples of solvents used for producing the solution of p-t-butoxystyrene include aromatic hydrocarbons such as benzene, toluene and xylene, aliphatic hydrocarbons such as hexane, heptane, cyclohexane and methylcyclohexane, ethers such as tetrahydrofuran, 1, 4-dioxane and ethyleneglycol dimethylether, and mixtures of two or more of them. The solvent used for producing the solution of p-t-butoxystyrene may be either same as or different from the reaction solvent.
Amount of the solvent used for producing a solution of p-t-butoxystyrene is preferably about 0.05-10 times by weight, more preferably about 0.1-1 time by weight, based on the amount of p-t-butoxystyrene.
The water content in the p-t-butoxystyrene or a solution thereof used in the present invention is in a range of 5-70 ppm. If the water content exceeds 70 ppm, poly(p-t-butoxystyrene) having narrow molecular weight distribution is hardly obtained. Upper limit of the water content is preferably 60 ppm, more preferably 50 ppm.
On the other hand, a specific drying agent, a complicated purification process or the like is required in order to obtain p-t-butoxystyrene or a solution thereof having water content of less than 5 ppm. Therefore, such a low water content is not favorable. Lower limit of the water content is preferably 10 ppm
The water content can be measured easily according to Karl Fischer method or the like.
P-t-butoxystyrene usually available contains some water which came, for example, from the atmosphere during its preservation. Therefore, when p-t-butoxystyrene is added singly to a mixture of a reaction solvent and a polymerization initiator, it is usually required to adjust the water content in p-t-butoxystyrene to the range defined in the present invention before adding the p-t-butoxystyrene. The water content can be adjusted to the range of 5-70 ppm, for example, by a distillation under a reduced pressure, or by a drying in which a drying agent such as molecular sieve, silica gel or the like is used. The drying in which a drying agent is used is convenient.
Similarly, a solvent used for producing a solution of p-t-butoxystyrene often contains some water which came, for example, from the atmosphere during its preservation. Therefore, when a solution of p-t-butoxystyrene is added to a mixture of a reaction solvent and a polymerization initiator, it is often required to adjust water content in the solution of p-t-butoxystyrene to the range defined in the present invention before adding the solution.
A solution of p-t-butoxystyrene having water content in a range of 5-70 ppm can be produced, for example, by a method in which p-t-butoxystyrene and the solvent are mixed, then the mixture is dried by a drying agent such as molecular sieve, silica gel or the like, or by a method in which p-t-butoxystyrene dried according to the above method and a solvent previously dried with a drying agent such as molecular sieve, silica gel or the like are mixed.
In the present invention, poly(p-t-butoxystyrene) is produced by a polymerization of p-t-butoxystyrene using one or more of reaction solvents and one or more of polymerization initiators. The polymerization reaction is conducted by adding p-t-butoxystyrene
Sughrue Mion Zinn Macpeak & Seas, PLLC
Sumitomo Chemical Company Limited
Teskin Fred
LandOfFree
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