Method for producing organic phosphorous compounds...

Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus containing

Reexamination Certificate

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Reexamination Certificate

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07851656

ABSTRACT:
Method of producing compounds of the general formulain-line-formulae description="In-line Formulae" end="lead"?XPR2(OR1)  Iain-line-formulae description="In-line Formulae" end="tail"?where X is chlorine, bromine or iodine and R1is an organic radical, by reacting compounds of the general formulain-line-formulae description="In-line Formulae" end="lead"?X2PR2  II,in-line-formulae description="In-line Formulae" end="tail"?in which X has the meaning given above and R2is an organic radical, with compounds of the general formulain-line-formulae description="In-line Formulae" end="lead"?R1OH  III,in-line-formulae description="In-line Formulae" end="tail"?in which R1has the meaning given above, to give a mixture IV, in thata) the postreaction is carried out at a temperature of from 50 to 240° C. and a pressure of from 0.001 to 0.9 bar,b) from the mixture IV the compounds Ia are separated off from the compoundsin-line-formulae description="In-line Formulae" end="lead"?PR2(OR1)2  Ibin-line-formulae description="In-line Formulae" end="tail"?and, if appropriate, the compounds II andc) compounds Ib and, if appropriate, unreacted compounds II are returned to the synthesis stage.

REFERENCES:
patent: 4661615 (1987-04-01), Boyle et al.
patent: 2004/0106815 (2004-06-01), Ritter
patent: 2005/0020857 (2005-01-01), Volland et al.
patent: WO 01/32666 (2001-05-01), None
patent: WO-01/32666 (2001-05-01), None
patent: WO-03/062251 (2003-07-01), None
Pastor et al., {Sterically hindered phosphonites, Phosphorus and Sulfur and the Related Elements,(1985), 22(2), 169-176}.
Herberich, G.E., et al., “1,1′-Bis(methylphenylphosphanyl)ferrocene: synthesis and complexes with the tetracarbonylchromium fragment,” Chem. Ber., 1995, vol. 128, pp. 689-693.
Pastor, S.D., et al., “Sterically hindered phophonites,” Phosphorus and Sulfur, 1985, vol. 22, pp. 169-176.

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