Method for producing octadienols

Details Method for producing octadienols Method for producing octadienols

1993-09-03

1994-04-26

Lone, Werren B.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

568 17, 568848, C07F 1500

Patent

active

053068351

ABSTRACT:
A method for producing octadienols, which comprises reacting 1,3-butadiene with water in the presence of a palladium compound, a phosphine compound and carbon dioxide, wherein a compound of the formula (I): ##STR1## wherein each of R.sup.1, R.sup.5 and R.sup.9 which may be the same or different, is a hydrocarbon group, and each of R.sup.2, R.sup.3, R.sup.4, R.sup.6, R.sup.7, R.sup.8, R.sup.10, R.sup.11 and R.sup.12 which may be the same or different, is hydrogen or a substituent, provided that at least one of them is an electron donative substituent, is used as the phosphine compound.

REFERENCES:
patent: 4945174 (1990-07-01), Hauser et al.
patent: 4990698 (1991-02-01), Wada et al.

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