Method for producing (meth) acrylic acid esters

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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Reexamination Certificate

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10479562

ABSTRACT:
The invention relates to a method for producing (meth)acrylic acid esters IV by means of transesterification of a (meth)acrylic acid ester I with an alcohol R2OH comprising at least one more carbon atom than the alcohol constituents (R1O—) in the (meth)acrylic acid ester I to be subjected to transesterification, in the presence of a catalyst or a catalyst mixture. Either essentially the (meth)acrylic acid ester I is separated and then the catalyst used is separated by distillation (catalyst separation), or the catalyst used is separated by distillation first (catalyst separation), and then essentially the (meth)acrylic acid ester I is separated, from the reaction product of the transesterification. Constituents from the mixture obtained, which have a lower boiling point than the (meth)acrylic acid ester IV, are essentially separated by distillation (separation of constituents at low boiling point), and the (meth)acrylic acid ester IV is then purified by distillation (purification by distillation).

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ORGANIKUM, vol. 17, Veb DT. Verlag Der Wissenschaften, Berlin, pp. 506-507 1988.
Ullmann's Encyclopedia of Industrial Chem., 6thed. Electronic Release, “Acrylic Acid and Derivatives” 1999.

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