Method for producing meltable polyesters

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

Reexamination Certificate

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Details

C264S176100, C264S219000, C428S364000, C525S088000, C525S089000, C525S090000, C525S397000, C525S398000, C525S271000

Reexamination Certificate

active

07009027

ABSTRACT:
This invention relates to a method for producing and processing polyester block copolymers, in particular, polyester side-chain grafted, rigid side-chain and/or semi-rigid side-chain polymers. According to the invention, the monomeric units of rigid side-chain and/or semi-rigid side-chain polymers are, preferably in the melt, polycondensated together with monofunctionalized and/or difunctionalized, cyclic dicarboxylic acid anhydrides to form polymers having anhydride terminal and/or side groups. The formed polyester anhydrides are reacted with the hydroxyl groups and/or with the ester groups of meltable linear polyesters in order to form side-chain grafted, rigid side-chain and/or semi-rigid side-chained polymers and, together with meltable polyesters, they form molecularly reinforced blends. These blends can be shaped into filaments or fibers having a high orientation of the reinforcing polymer or they serve as compatibility mediators in blends consisting of a polyester matrix and of rigid side-chain and/or semi-rigid side-chain polymers. The filaments are used, in particular, in technical fields or in the carpet industry.

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Gabor KissIn Situ Composites: Blends of Isotropic Polymers and Thermotropic Liquid Crystalline PolymersPolymers Engineering and Science Mar., 1987, vol. 27, No. 6, pp. 410-423.
Datta et al. Annu. Tech. conf.-Soc. Plastic Eng., 49th, pp. 913-918.
Höcker et al. Makromol. Chem. 190 (1989), pp. 3294-3316.

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