Method for producing high surface area chromia materials for...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Cellular products or processes of preparing a cellular...

Reexamination Certificate

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C521S064000, C521S181000, C524S430000, C423S596000, C423S607000, C502S300000, C502S319000

Reexamination Certificate

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10132803

ABSTRACT:
Nanostructured chromium(III)-oxide-based materials using sol-gel processing and a synthetic route for producing such materials are disclosed herein. Monolithic aerogels and xerogels having surface areas between 150 m2/g and 520 m2/g have been produced. The synthetic method employs the use of stable and inexpensive hydrated-chromium(III) inorganic salts and common solvents such as water, ethanol, methanol, 1-propanol, t-butanol, 2-ethoxy ethanol, and ethylene glycol, DMSO, and dimethyl formamide. The synthesis involves the dissolution of the metal salt in a solvent followed by an addition of a proton scavenger, such as an epoxide, which induces gel formation in a timely manner. Both critical point (supercritical extraction) and atmospheric (low temperature evaporation) drying may be employed to produce monolithic aerogels and xerogels, respectively.

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Gash et a.l, “New sol-gel Synthetic Route to Transition and main-group Metal Oxide Aerogels Using Inorganic Salts Precursors”, J. Non-Cryst. Solids, vol. 285, pp. 22-28.
Skapin et al., “Fluorination effects in Chroma Aerogels and Xerogels”, J. Non-Cryst. Solids, vol. 225, pp. 163-167.

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