Method for producing graft copolymers of cellulose or protein fi

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 174GC, 260 174SG, C08L 102, C08L 8900

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active

042293260

ABSTRACT:
A method for obtaining graft copolymers of cellulose or protein fiber with vinyl monomers, comprising the steps of impregnating cellulose or protein fiber with an aqueous solution of ferrous salt, removing excessive ions of ferrous iron, and grafting vinyl monomers to cellulose or protein fiber from an aqueous solution, aqueous emulsion or aqueous dispersion of a vinyl monomer, containing hydrogen peroxide and a reducing agent. The latter is hydrazine sulfate, sodium sulfide, glucose, sodium hypophosphite, sodium bitartrate or hydroquinone taken in an amount of 0.002 to 0.02 percent by mass. The method provides for a high rate of graft polymerization and rules out the formation of a free homopolymer in the reaction mixture. It can be carried out as a continuous and batch process.

REFERENCES:
patent: 4036588 (1977-07-01), Williams et al.
patent: 4066583 (1978-01-01), Spaulding
C.A. vol. 67: 65621f, Continuous Polymer Deposition on Cellulose, Rose.
C.A. vol. 71: 71782h, Iron Ion Adsorption--Vinyl Monomers, Cremonesi.
C.A. vol. 71: 125,905w, Grafting--Support--Protein Fibers, Habib.
C.A. 83: 29686c, Graft Copolymers--Protein--Vinyl Monomers--Redox System, Butina et al.
C.A. 88: 106619r, Study--Structure--Grafted Cellulose Co-polymers, Morin et al.

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