Method for producing elastomeric copolyesters

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

Reexamination Certificate

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C528S271000, C528S272000, C528S297000, C528S301000, C528S307000, C528S491000, C528S497000, C528S498000, C526S072000, C526S077000, C540S538000, C525S010000, C525S050000

Reexamination Certificate

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07829654

ABSTRACT:
A process for continuous or discontinuous synthesis of elastomeric copolyesters from polybutylene terephthalate (PBT) and polyoxytetramethylene glycol is described in which the tetrahydrofuran (THF) obtained as a byproduct in synthesis of polybutylene terephthalate from 1,4-butanediol is rectified and then reacted by ring-opening polymerization to form polyoxytetramethylene glycol which condenses with the free or esterified carboxyl groups of PBT to form the copolyester, whereby chain termination and catalyst deactivation are accomplished by adding 1,4-butanediol without separating the catalyst.

REFERENCES:
patent: 3050533 (1962-08-01), Maclean et al.
patent: 4081494 (1978-03-01), Sakai
patent: 06057630 (1994-03-01), None
patent: 08231706 (1996-09-01), None
patent: WO9511267 (1995-04-01), None
Machine translation of JP 06-057630.
Machine translation of JP 08-231706.

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