Method for producing dinitriles

Organic compounds -- part of the class 532-570 series – Organic compounds – Nitriles

Reexamination Certificate

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Reexamination Certificate

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07816551

ABSTRACT:
An adiponitrile/methylglutaronitrile preparation process includes distilling a reaction stream to obtain stream3depleted in pentenenitriles (bottom product) and stream4enriched in pentenenitriles (top product); extracting stream3obtaining stream6enriched with extractant (top product) and stream7depleted in extractant (bottom product); distilling stream6obtaining stream8comprising the catalyst (bottom product) and stream9comprising the extractant (top product); distilling stream7obtaining stream10(bottom product) and stream11comprising the extractant (top product); distilling stream10obtaining stream12comprising catalyst degradation products, at least one promotor, adiponitrile and methylglutaronitrile (bottom product) and stream13comprising pentenenitriles (top product); distilling stream12obtaining stream14comprising catalyst degradation products and the promotor(s) (bottom product) and stream15comprising adiponitrile and methylglutaronitrile (top product); distilling stream15obtaining stream16comprising adiponitrile (bottom product) and stream17comprising methylglutaronitrile (top product).

REFERENCES:
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patent: 3752839 (1973-08-01), Drinkard, Jr. et al.
patent: 3766241 (1973-10-01), Drinkard
patent: 3773809 (1973-11-01), Walter
patent: 3852325 (1974-12-01), King
patent: 3852327 (1974-12-01), Druliner et al.
patent: 4080374 (1978-03-01), Corn
patent: 4385007 (1983-05-01), Shook, Jr.
patent: 5723641 (1998-03-01), Tam et al.
patent: 0 464 691 (1992-01-01), None

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