Method for producing cyclohexanone and alkyl-substituted or unsu

Details Method for producing cyclohexanone and alkyl-substituted or unsu Method for producing cyclohexanone and alkyl-substituted or unsu

1976-01-22

1977-03-01

Morgenstern, Norman

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260621G, C07C 2712, C07C 3700, C07C 4502

Patent

active

040102068

ABSTRACT:
Both cyclohexanone and alkyl-substituted or unsubstituted phenol are simultaneously produced, in a one step reaction, by oxidizing, in the liquid phase, an alkyl-substituted or unsubstituted phenylcyclohexane of the formula (I): ##STR1## wherein R represents either a hydrogen atom or a methyl radical with an oxidizing gas containing molecular oxygen therein in the presence of hydrogen bromide.

REFERENCES:
patent: 2380675 (1945-07-01), Rust et al.
patent: 3360572 (1967-12-01), Selwitz
patent: 3846499 (1974-11-01), Riedl
Redoshkin et al., "Trudy pokhim. i Khim. Tekhnol.", 3, No. 1, 3-8 (1960) C.A. 56:1367f.
Rummel et al., "J. Prakt. Chem," 37(3-4), 206-213, (1968) C.A. 68:77413y.
Schiketanz et al., "Rev. Roum. Chim", 1968, 13(10), 1385-1390, CA. 70:67806f.
Farberov et al, "Miflekhumuya", 1969, 9(1), 107-115 CA 71:21755f.
"Uki. Khim. Zh", 30, 1073-1075 (1976).

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