Method for producing cyclic organic silicon compound and...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From silicon reactant having at least one...

Reexamination Certificate

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C556S464000

Reexamination Certificate

active

07402648

ABSTRACT:
The object of the present invention is to provide a production method wherein synthesis of a cyclic organic silicon compound similar to oxa-silacyclopentanes is completed in a single-step reaction. It is also to provide an organic silicon resin having an alcoholic hydroxyl group, which is capable of easily controlling its construction and is longitudinally stable.The means for solving is to produce the cyclic organic silicon compound represented by the formula (3) below by reacting an olefin represented by the formula (1) below and an alkoxysilane represented by the formula (2) below in the presence of a catalyst comprising a transition metal.(In the formula, Z is alkenyl group having carbon atoms from 2 to 5 where the terminal carbon atom forms a C═C bond, R is methyl group or hydrogen atom, and Me is methyl group.)(In the formula, R1is alkyl group or alkoxyl group, having carbon atoms from 1 to 3, and R2is alkyl group having carbon atoms from 1 to 3.)(In the formula, Z′ is alkylene group having carbon atoms from 2 to 5.)And it is an organic silicon resin having an alcoholic hydroxyl group obtained by performing hydrolysis and condensation of a cyclic organic silicon compound represented by the formula (3) above, or of a mixture of this and a polyfunctional alkoxysilane.

REFERENCES:
patent: 3539610 (1970-11-01), Abe
patent: 4924021 (1990-05-01), Kotzsch et al.
patent: 5124468 (1992-06-01), Krafft et al.
patent: 5191102 (1993-03-01), Oyama et al.
patent: 5520767 (1996-05-01), Larson
patent: 5595593 (1997-01-01), Burns et al.
patent: 5856392 (1999-01-01), Kennedy et al.
patent: 5861468 (1999-01-01), Harkness et al.
patent: 6774202 (2004-08-01), Lee
patent: 2004/0082681 (2004-04-01), Brand et al.
patent: 2007/0184006 (2006-08-01), Ferenz et al.
patent: 7 149901 (1995-06-01), None
patent: 8 231924 (1996-09-01), None
patent: 9 176321 (1997-07-01), None
patent: 10 87834 (1998-04-01), None
patent: 11 116681 (1999-04-01), None
patent: 2001 213963 (2001-08-01), None
patent: 2002 249493 (2002-09-01), None
patent: 2002 338583 (2002-11-01), None
patent: 2003 98670 (2003-04-01), None
patent: 2003 146832 (2003-05-01), None
patent: 2003 149822 (2003-05-01), None
Trost et al., “Markovnikov Alkyne Hydrosilylation Catalyzed by Ruthenium Complexes”, Journal of the American Chemical Society, vol. 123, No. 50, pp. 12726-12727, 2001.
Walkup et al., “Effects of Variations of Alkoxy Substituents Upon Cyclizations of Dialkoxy-2-Chloroethylsilyl Enol Ethers to Form 2,2-Dialkoxy-1-Oxa-2-Silacyclohexanes1”, Chemistry Letters, No. 7, pp. 1055-1058, 1990.
Tanino et al., “Control of Stereochemistry by σ-Participation of a Silyl Group. A Novel Method for Diastereoselective Polyol Synthesis”, J. Org. Chem., vol. 62, pp. 4206-4207, 1997.
Bear et al., “Diastereoselective Nucleophilic Substitution Reactions of Oxasilacyclopentane Acetals: Application of the “Inside Attack” Model for Reactions of Five-Membered Ring Oxocarbenium Ions”, J. Org. Chem., vol. 67, pp. 2056-2064, 2002.
Rossmy et al., “1,2-Siloxacycloalkane- 1. Mitt. Synthese und Polymerisationsverhalten”, Makromolekulare Chemie, vol. 73, pp. 85-108, 1964.
Koerner et al., 1,2-Siloxacycloalkane- 2. Mitt Synthese und Chemisches Verhalten Von 1,1′-DI-(1-Methyl-1,2-Siloxacyclopentyl)-Oxid*, Makromolekulare Chemie, vol. 97, pp. 241-247, 1996.

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