Method for producing concentrated nitric acid and...

Distillation: processes – separatory – Distilling to separate or remove only water – From nitric acid

Reexamination Certificate

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C159S002100, C159S023000, C159S047100, C159SDIG019, C159SDIG020, C202S154000, C202S173000, C202S235000, C202S205000, C203S022000, C203S025000, C203S078000, C203S079000, C203S080000, C203S088000, C203S050000, C423S390100

Reexamination Certificate

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06969446

ABSTRACT:
Process for producing a nitric acid of a concentration from 75 to 99.9% from a more diluted nitric acid, wherein a nitric acid of a concentration of about 45 to 70% is rectified in contact with a liquid extraction medium to prevent the formation of a nitric acid-water-azeotropic mixture, and the vapors of the concentrated nitric acid are condensed and a concentrated nitric acid is obtained and wherein additionally the extraction medium is reconstituted through reconcentration and returned into the extractive rectification, wherein the nitric acid to be concentrated is fed as a boiling liquid or partially vaporized to the extractive rectification preferably carried out in two columns (K1.0, K1.1), by utilizing the amounts of heat available to the entire process (W1, W2, W5), wherein, before feeding into the extractive rectification nitric acid is added to the extraction medium, and the energy required for the extractive rectification is supplied through indirect heating (W4, W8) and the extraction medium supplied in most concentrated form to the extractive rectification, so that simultaneously at the greatest possible dilution of the extraction medium flowing from the extractive rectification, the circulation amount of extraction medium is minimized and the utilization of energy maximized.

REFERENCES:
patent: 1163174 (1915-12-01), Raschig
patent: 1895492 (1933-01-01), Shapleigh
patent: 1921255 (1933-08-01), Hechenbleikner
patent: 1922289 (1933-08-01), Handforth
patent: 4966276 (1990-10-01), Guenkel
patent: 5589037 (1996-12-01), Guggenheim et al.
patent: 305553 (1917-05-01), None
patent: 1 056 095 (1959-04-01), None
patent: 0 330 351 (1989-08-01), None
patent: 2.003.298 (1969-11-01), None
Schott-Engineering, published by Schott-Engineering GmbH, Germany.
Salpetersäure, in: Ullmanns Enzyklp[ädie der technischen Chemie, 4th Edition, vol. 20, pp. 324-326.

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