Method for producing chemically stable urea-formaldehyde foams

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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260 70R, 260 71, 260849, C08J 930, C08J 912

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active

040922774

ABSTRACT:
Method of producing a substantially chemically stable urea-formaldehyde foam which comprises preparing a partially cured aqueous urea-formaldehyde resin, modifying the partially cured resin by reacting at pH 4.5 - 5.5 and 70.degree.-110.degree. C with aqueous dialdehyde containing two to six molecular carbons and additional urea with each additive amounting to 1-5 per cent by weight of the modified resin, neutralizing the modified resin to pH 6.7 - 7.5 by addition of aqueous alkali hydroxides or carbonates, combining said neutral modified resin with a froth produced by forcing air through a dilute acidic aqueous surfactant solution to re-activate and complete the cure of the modified resin in the foam, and drying the foam.
Glyoxal is the preferred dialdehyde for modifying the urea-formaldehyde foam resin because of its effectiveness at increasing chemical stability of the foam at levels as low as 1.0 per cent.

REFERENCES:
patent: 2559891 (1951-07-01), Meyer
patent: 3256067 (1966-06-01), Shriver et al.
patent: 3377139 (1968-04-01), MacGregor et al.

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