Method for producing aryl alkyl hydroperoxides

Details Method for producing aryl alkyl hydroperoxides Method for producing aryl alkyl hydroperoxides

1996-02-27

1998-12-08

Shah, Mukund J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568910, 5689105, 562512, 562549, 540474, C07C 4532, C07C 4533

Patent

active

058472274

ABSTRACT:
A method for producing aryl alkyl hydroperoxides which comprises selectively oxidizing an aryl alkyl hydrocarbon having the formula: ##STR1## wherein P and Q are hydrogen or an alkyl and may be the same or different from each other; x is an integer of 1-3; and Ar is an aromatic hydrocarbon group having a valence of x, with an oxygen-containing gas in the presence of a transition metal complex which contains, as a ligand, a cyclic polyfunctional amine compound having at least three nitrogen atoms in the ring forming molecular chain or an open chain polyfunctional amine compound having at least three nitrogen atoms in the main chain of the molecule.

REFERENCES:
patent: 4459427 (1984-07-01), Middleton et al.
Chemical Abstracts, vol. 78, No. 21, Abstract No. 135806, XP002032832, Columbus, Ohio, US; May 28, 1973.
Chemical Abstracts, vol. 79, No. 9, Abstract No. 52880, XP002032833, Columbus, Ohio, US; Sep. 3, 1973.
Database WPI Week 7534, AN 75-56360, XP002032834, Derwent Publications Ltd., London, GB;.
Chemistry Letters, vol. 2, pp. 103-106, Hara et al.: "Oxidation of Cumene", 1973.
Database WPI Week 7534, AN 75-56360, XP002032834, Derwent Publications Ltd., London, GB, Apr. 8, 1975.

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