Coating processes – Electrical product produced – Condenser or capacitor
Reexamination Certificate
2000-11-28
2003-05-06
Talbot, Brian K. (Department: 1762)
Coating processes
Electrical product produced
Condenser or capacitor
C427S126100, C427S372200, C029S874000, C029S025030, C029S025410
Reexamination Certificate
active
06558737
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method for producing an electrode for a capacitor, the capacitor having an electrode charge eliminator and a body contacted therewith, wherein an electrode body having a dielectric layer on its surface is formed by oxidizing a surface layer of the body. Furthermore, the present invention relates to a method for producing the capacitor.
2. Description of the Prior Art
Methods for producing electrodes for capacitors are known wherein, on the basis of a porous sintered body made of niobium, an anodic oxidation is carried out on the surface of the sintered body. A dielectric layer composed of Nb
2
O
5
thereby forms on the surface of the sintered compact.
The known methods with respect to niobium capacitors have the disadvantage that the capacitors produced therewith do not have sufficient long-time stability. This results from oxygen from the dielectric layer diffusing into the metallic niobium of the sintered compact, so that suboxides exhibiting semiconducting (NbO
2
) or, respectively, electrically conducting (NbO) properties are formed in the oxide layer as a result thereof. As such, the dielectric becomes effectively thinner, such that electric strength is lost and the capacitor fails.
Therefore, the present invention is directed to providing a method for producing an electrode for capacitors which has a high long-time stability.
SUMMARY OF THE INVENTION
Accordingly, the present invention proposes a method enabling the production of an electrode with an electrode body, of an electrode charge eliminator contacted therewith, of a dielectric layer on the surface of the electrode body and of an immediate layer between the dielectric layer and the electrode body.
Pursuant to the inventive method, an electrode charge eliminator and a body contacted therewith are taken as a basis—the body being made of a material with a component A and a component B. The components are selected such that the component A is a conductive material whose surface can be transformed into a dielectric by oxidation. Furthermore, the components are selected such that the absolute amount of the free enthalpy &Dgr;G of the oxidation is greater with respect to the component A than with respect to the component B. As a result, the component A is preferably oxidized at the surface. Finally, the surface energy of the component A must be greater than the surface energy of the component B, this being a secondary condition.
On the basis of the described material compound, the following steps are carried out:
a) the component A of the material is oxidized in a surface layer of the body, so that an electrode body having a dielectric layer on its surface is formed; and
b) subsequently, the electrode body is treated with heat at a suitable temperature until the component B of the material segregates at the surface of the electrode body—there, the component B forms an intermediate layer between the electrode body and the dielectric layer.
Furthermore, the present invention proposes a method for manufacturing a capacitor which includes the following steps:
c) covering the surface of the pores of the electrode with a counter electrode; and
d) contacting the counter electrode with a counter electrode charge eliminator.
Due to a suitable selection of the component B, the intermediate layer of the inventive electrode can be functionally formed such that it stops the exchange of matter between the dielectric layer and the electrode body.
The inventive method has the advantage that the material, of which the intermediate layer is formed, is present as the component of the body material. Thus, the material of the intermediate layer can be very easily introduced into the method; for example, in the form of a homogenous alloy.
The energetic requirements for forming the oxides of the components A and B are met, for example, by niobium as the component A and by vanadium as the component B. Given niobium (Nb
2
O
5
), the free enthalpy &Dgr; of the oxidation is &Dgr;Gox=−210.5 kcal/mol. The free enthalpy of the oxidization of vanadium is (V
2
O
5
)&Dgr;Gox=−135.7 kcal/mol. This means, in the case of an oxidization caused by an anodic oxidization, for example, that Nb
2
O
5
will preferably form and not V
2
O
5
. It is therefore assured that the dielectric layer of the electrode, by an oxidation-induced segregation, is preferably formed of the material of the component A, which is suitable therefor.
If niobium is selected as the component A and vanadium as the component B, the correct ratio of sizes is received for the respective surface energies. The surface energy of niobium is &ggr;=2.983 Jm
−2
, whereas the surface energy of vanadium is &ggr;=2.876 Jm
−2
. It is thereby achieved that the component B having the weaker surface energy enriches itself by segregation at the surface of the electrode body, namely between the dielectric layer and the electrode body, as a result of the heat treatment carried out after the oxidization.
Therefore, the inventive method has the advantage that the component B, by the very simple heat treatment and without additional measures, can be transported to the desired location; namely, between the surface of the electrode body and the dielectric layer.
In an advantageous embodiment of the method of the present invention, the component B can be selected such that the intermediate layer formed by it blocks the exchange of oxygen between the dielectric layer and the electrode body. For this purpose, it is necessary that the diffusion rate of oxygen in the component B is lower than in the component A and that the oxygen in the component B does not dissolve as well as in the component A. This condition is fulfilled in that niobium is selected as the component A and vanadium as the component B. As a result of such an intermediate layer blocking the diffusion of oxygen, the forming of suboxides by depletion of oxygen in the dielectric layer composed of Nb
2
O
5
can be effectively prevented.
As a material for the inventive method, a metallic alloy can be advantageously utilized, wherein the portion of the component B typically is between 10 and 50 weight percent—ppm. Given the utilization of niobium as component A and vanadium as component B, it is particularly simple in terms of production to provide the mixture in the form of an alloy, since metals are used in both cases. The component B also can be present in the form of a dopant in the material.
Moreover, a valve metal such as niobium or tantalum, or also a valve-metalliferous alloy such as a niobium/tantalum alloy, also can be utilized given the material of the body for the component A. In the case of the component A representing a niobium/tantalum alloy, a mixed oxide with particularly advantageous properties would be received for the dielectric layer.
Preferably, the body used in the method can be a porous body which is produced by sintering a powder or paste, for example. The utilization of a porous body as an electrode body has the advantage of a large surface, so that the capacitor produced with the electrode has a high capacitance.
For purposes of reducing the oxygen diffusion between the dielectric layer and the electrode body, a component B containing scandium, yttrium, a lanthanide, titanium, zirconium vanadium, chromium, wolfram (Tungsten) or molybdenum is particularly considered. Lanthanides such as lanthanum, cerium, praseodymium, neodymium, polonium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, ytterbium or lutetium also can be considered.
It is also particularly advantageous to select the portion of the component B with respect to the material of the body, as well as the duration and temperature of the heat treatment for the electrode body, such that an intermediate layer having a thickness of at least two atomic monolayers arises. The production conditions for the anode body, for example by extending the heating duration or by increasing the heating temperature, also can be sel
Giber Janos
Stenzel Melanie
Zillgen Holger
Bell Boyd & Lloyd LLC
EPCOS AG
Talbot Brian K.
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