Method for producing ammonia from methanol

Chemistry of inorganic compounds – Nitrogen or compound thereof – Ammonia or ammonium hydroxide

Reexamination Certificate

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C252S375000, C423S360000, C564S069000

Reexamination Certificate

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07547428

ABSTRACT:
Ammonia is catalytically produced from a nitrogen-hydrogen mixture. First of all, a vaporous feed mixture, which comprises 30 to 60 vol-% methanol and 40 to 70 vol-% steam and has a volume ratio steam:methanol of 1 to 3, is passed through at least one bed of a breakdown catalyst at pressures in the range from 30 to 200 bar, the temperatures in the catalyst bed lying in the range from 200 to 500° C. From the catalyst bed, a first gas mixture is withdrawn, which, calculated dry, comprises 40 to 80 vol-% H2and 10 to 30 vol-% CO2. The first gas mixture is cooled, CO2is removed in a gas cleaning, and a second gas mixture is generated, which comprises at least 95 vol-% nitrogen and hydrogen, and which is supplied as synthesis gas to an ammonia synthesis for the catalytic production of ammonia.

REFERENCES:
patent: 2002/0098132 (2002-07-01), Vidalin
patent: 2003/0099593 (2003-05-01), Cortright et al.
patent: 20 07 441 (1971-09-01), None
patent: 0 303 032 (1989-02-01), None
patent: 0 307 983 (1989-03-01), None
patent: 0 311 932 (1989-04-01), None
patent: 0 931 762 (1999-07-01), None
Ullmann's Encyclopedia of Industrial Chemistry, 5thedition, vol. A2, pp. 143-215.
Ullmann's Encyclopedia of Industrial Chemistry, 5thedition, vol. A27, pp. 333-350.
Patent Abstracts of Japan, vol. 015, No. 457 (M-1181) Nov. 20, 1991 & JP 03 194111 A (Shinnenshiyou Syst Kenkyusho:KK) Aug. 23, 1991.

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