Method for producing aluminum metal from aluminum trichloride

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Utilizing fused bath

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205394, C25C 306

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active

060662476

ABSTRACT:
A method is provided for the electrolytic production of aluminum metal from aluminum trichloride starting material. A molten electrolytic solution of mixed chloride-fluoride salts is formed in a reaction vessel into which the aluminum trichloride feed material is added. The fluoride component of the electrolyte reacts spontaneously with the aluminum trichloride, producing aluminum fluoride and a chloride salt. The aluminum fluoride is advantageously stored in a non-volatile state in solution in the electrolyte. The aluminum fluoride is then electrolytically reduced to yield aluminum metal and a fluoride salt.

REFERENCES:
patent: 3103472 (1963-09-01), Slatin
patent: 3518172 (1970-06-01), Layne et al.
patent: 3725222 (1973-04-01), Russell et al.

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