Method for producing alpha, beta-unsaturated calboxylic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

Reexamination Certificate

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C562S533000

Reexamination Certificate

active

08058473

ABSTRACT:
Disclosed is a method for producing an α, β-unsaturated carboxylic acid from an olefin or an α, β-unsaturated aldehyde, while suppressing dissolution of a silica carrier, which is a carrier for a silica-supported noble metal-containing catalyst, in a water-containing solvent. Specifically disclosed is a method for producing an α, β-unsaturated carboxylic acid through oxidation of an olefin or an α, β-unsaturated aldehyde in a water-containing solvent in the presence of a silica-supported noble metal-containing catalyst in a reactor, in which at least one of silicic acid and ions thereof is supplied into the reactor.

REFERENCES:
patent: 3624147 (1971-11-01), David et al.
patent: 3969274 (1976-07-01), Frampton
patent: 4404397 (1983-09-01), Daniel
patent: 2002/0151747 (2002-10-01), Unruh et al.
patent: 2007/0173662 (2007-07-01), Fujimori et al.
patent: 2007/0238903 (2007-10-01), Ninomiya et al.
patent: 2005 075072 (2005-08-01), None
patent: 2005 118134 (2005-12-01), None
Hawley Gessner, the Condensed Chemical Dictionary ,1975,Van Nostrand Reinhold Co., 8th ed.,p. 783.

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