Coating processes – Spray coating utilizing flame or plasma heat – Metal oxide containing coating
Reexamination Certificate
1999-01-22
2001-05-22
Beck, Shrive (Department: 1762)
Coating processes
Spray coating utilizing flame or plasma heat
Metal oxide containing coating
C427S595000, C427S597000, C427S576000, C427S446000, C588S253000
Reexamination Certificate
active
06235351
ABSTRACT:
FIELD OF THE INVENTION
The present invention relates to the treatment of hazardous contamination in general, and in particular to thermal-spray surface-deposition methodology for the production of a self-decontaminating photocatalytic surface capable of neutralizing hazardous organic chemicals and biologicals through reaction with hydroxyl radicals produced from the interaction of a transition metal oxide and water in the presence of ultraviolet light.
BACKGROUND OF THE INVENTION
Contamination of exposed structural surfaces with dangerous chemical or biological material creates a critical threat in both civilian and military contexts. In the former context, such civilian contamination can occur accidentally, such as during the conveyance of hazardous materials from one site to another, or the civilian contamination can occur on purpose, such as where a community becomes the target of hostility. In the military context, chemical and/or biological warfare can, for instance, occur under test conditions, or it can be present as an actual peril during active conflict. In any event, such deployed materials can remain for a significant period of time (e.g. up to several weeks) on exposed surfaces such as vehicles, aircraft, buildings, equipment, etc., and thereby remain as dangers to humans and animals that may come in contact with these surfaces before decontamination is undertaken.
One present decontamination procedure includes the application of cleaning agents generally coupled with actual scrubbing of surfaces. Because of the nature of the contaminants, extreme care must be taken to make certain that any water supply systems, as well as fisheries, domestic and wild animal water sources, and the like, do not become infiltrated because contaminated cleaning agents are rinsed into the sewer system or ground and eventually return in supposedly fresh water for subsequent consumption. A second present decontamination procedure is the application of a fixed coating of titanium dioxide nanoparticles on an exposed surface for subsequent decontamination through ultraviolet catalytic generation of hydroxyl radicals. However, and while such a coating is effective in achieving decontamination, its universality of application under present methodology is severely limited because coating procedures presently taught do not result in efficient, uniform, and rapid particulate deposition.
Thus, in view of the criticality of adequate care and the danger present in exercising that care when dealing with hazardous chemicals and biologicals, it is apparent that a need is present for methodology that can accomplish decontamination of these hazardous substances without severe interference with normal societal activities. Accordingly, a primary object of the present invention is to provide methodology for creating a self decontaminating surface whereby a transition metal oxide can be efficiently and relatively widely deposited on a surface for subsequent reaction with water and catalytic ultraviolet light to yield hydroxyl radicals for decontaminating reaction with untoward contaminants.
Another object of the present invention is to provide deposition methodology that employs a thermal spray technique for coating transition metal oxide on a surface for subsequent decontamination.
Yet another object of the present invention is to provide deposition methodology for nanoparticle cluster impact of the transition metal oxide on the surface whereby the clusters break apart on impact to cause particle dispersion and adherence at the surface interface.
These and other objects of the present invention will become apparent throughout the description of the invention which now follows.
SUMMARY OF THE INVENTION
The present invention is a method for producing a self decontaminating surface to decontaminate chemical and biological contaminants that are decontaminatable through reaction with free hydroxyl radicals and that are deposited on the surface. The method first includes the determination of a surface to be treated and which is disposed to be exposable to ultraviolet light. Second, a coating of nanoparticles of a transition metal oxide, non-limitedly exemplified by anatase titanium dioxide, is applied to the chosen surface. Application of the coating is accomplished by spraying heated nanoparticles of the transition metal oxide from a feed stock onto the surface to form a nanoparticle coating, with the nanoparticles being at a temperature of at least about 750° C. upon exit from a spray apparatus and of a size between about 5 nm and 100 nm. Finally, the treated surface is exposed to ultraviolet light and water moisture to thereby catalytically form free hydroxyl radicals that thereafter react with the contaminants to render them generally harmless.
Generally, any surface can be established as a self decontaminating surface, and can include building structures, ships, aircraft, etc. such as those that may be involved in military operations where hazardous chemicals (e.g. solvents, nerve gases) and/or biologicals (e.g. bacteria, viruses) are potentially involved. A usual source of ultraviolet light is from sunlight, while a usual source of moisture is from ambient humidity. One non-limiting method for applying a nanoparticle coating is spraying a plurality of nanoparticle clusters onto the surface. These sprayed clusters strike the surface and immediately break apart to thereby provide relatively uniform nanoparticle surface coverage. Reaction between metal oxide molecules and water molecules, catalyzed by ultraviolet light, results in the liberation of free hydroxyl radicals available for decontamination reaction with chemical and biological contaminants to thereby render the surface safe. In this manner, exposed structural surfaces can be rapidly converted to self decontaminating surfaces that render innocuous the untoward chemical and biological precipitates there deposited.
REFERENCES:
patent: 2718473 (1955-09-01), Powers
patent: 3944683 (1976-03-01), Church et al.
patent: 4713646 (1987-12-01), Sunano et al.
patent: 5707915 (1998-01-01), Taoda
patent: 5939146 (1999-08-01), Lavernia
patent: 5952040 (1999-09-01), Yadav et al.
patent: 5990373 (1999-11-01), Klabunde
patent: 5997956 (1999-12-01), Hunt et al.
patent: 6025034 (2000-02-01), Strutt et al.
patent: 6057488 (2000-05-01), Koper et al.
DiMarzio Donald
Klein John F.
Pirich Ronald G.
Anderson Terry J.
Beck Shrive
Hoch, Jr. Karl J.
Kolb Jennifer
Northrop Grumman Corporation
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