Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1976-07-08
1978-03-28
Michl, Paul R.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260 4AR, 260 95C, 526 64, C08L 906, C08L 806
Patent
active
040814971
ABSTRACT:
In the method for producing a high impact polystyrene from a monomer of styrene or/and its derivative and a rubbery polymer as reactants, an improvement is provided which comprises passing said reactants through a tubular reactor having parts where the passage way of flow of said reactants is constricted, while keeping said reactants in a laminar flow as much as possible in the parts other than said parts, in a first stage polymerization to prepare a reacted mixture containing a prepolymer until the conversion of monomer to polymer becomes 10 to 60%, and subjecting the resulting reacted mixture to a second stage polymerization in the state where almost no shearing is exerted thereupon.
The shearing during said first stage polymerization can be uniformly carried out.
The resulting product has superior high impact properties.
REFERENCES:
patent: 3052664 (1962-09-01), Cleland
patent: 3054783 (1962-09-01), Lashua
patent: 3451986 (1969-06-01), Metais
patent: 3595846 (1971-07-01), Rouzier
patent: 3679651 (1972-07-01), Toshimichi
patent: 3980628 (1976-09-01), Sorenson
Konuma Hideo
Mochizuki Shigeaki
Okada Yoshio
Tokumitsu Ichiro
Yasumoto Hiroshi
Idemitsu Petrochemical Co. Ltd.
Michl Paul R.
Philpitt Fred
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