Method for producing 1,4-dihydroxy-2-naphthoic acid

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof

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C07C 5115

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055999719

ABSTRACT:
A method for producing 1,4-dihydroxy-2-naphthoic acid which comprises the steps of: subjecting 1,4-dihydroxynaphthalene into an alkali metal salt formation reaction in an organic medium capable of dissolving 1,4-dihydroxynaphthalene using an alkali metal alcoholate; and subjecting the salt formation reaction mixture to carboxylation using carbon dioxide gas.

REFERENCES:
patent: 1697332 (1929-01-01), Stenzl
patent: 2807643 (1957-09-01), Hartley
patent: 3825593 (1974-07-01), Meek
Lindsey, Chem. Rev., 57, pp. 583-620 (1957).
Homeyer et al, "A Study of Diethyl 1,4-Dihydroxy-2,3-Naphthalate," J. Am. Chem. Soc., vol. 64, p. 798, Apr. 1942.
J. Prakt. Chem., vol. 62, No. 2, p. 30, May 1900.

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