Method for processing etherified light hydrocarbon mixtures to r

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568699, 585518, 585519, 585717, 585800, 585832, C07C 4106, C07C 4112

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042185696

ABSTRACT:
Mixed hydrocarbons of predominantly four carbon atoms each are subjected to etherification with methanol, to make ether from the tertiary olefin in the mixture; the unreacted hydrocarbons, after separation from the ether by distillation, are contaminated with methanol which is removed by absorption or extraction with a glycol before the hydrocarbons are subjected to further processing in which the methanol is detrimental.

REFERENCES:
patent: 2542454 (1951-02-01), Arnold
patent: 2580750 (1952-01-01), Fleming
patent: 2671104 (1954-03-01), Grahame et al.
patent: 3388046 (1968-06-01), Hendrix
patent: 3726942 (1973-04-01), Louder
patent: 3846088 (1974-11-01), Brown et al.
Perry, Chemical Engineers Handbook, McGraw-Hill Book Co., New York, 4th ed., 1963, 14-40, 14-41, 14-42, 18-3.

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