Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...
Reexamination Certificate
2000-11-14
2002-09-17
Reddick, Judy M. (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
At least one aryl ring which is part of a fused or bridged...
C524S555000
Reexamination Certificate
active
06451891
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The invention relates to a method for preventing or retarding the formation of gas hydrates or for reducing the tendency of such hydrates to agglomerate during the transport of a fluid comprising water and a hydrocarbon through a conduit, and, more particularly, to the addition to the fluid of an N-alkyl(meth)acrylamide polymer, N,N-dialkyl(meth)acrylamide polymer and copolymers thereof with N-vinyl-N-methylacetamide, which are made and applied in a defined solvent, to inhibit such gas hydrate formation.
2. Description of the Prior Art
It is well known in the art that the formation of gas hydrates in a conduit, e.g. a pipeline, during the transport of liquids, such as oil, and gases, particularly lower hydrocarbons, e.g. methane, ethane, propane, butane, isobutane and natural gas is a serious problem, especially in areas with a low temperature in the winter season or in the sea. Generally the temperatures are so low that gas hydrate formation, due to the inevitable presence of co-produced water in the wells takes place, if no special steps are taken. Insulation decreases the chance of gas hydrate formation; however, if the field is relatively small and far away from the production platform, the costs of using insulation are too high to make such field economically attractive. It is also known to add anti-freeze compounds, for example, glycol or methanol, during transport to minimize gas hydrate formation; however, large quantities of these compounds are required to be effective which is expensive. Alkyl glycosides also have been used for this purpose.
A representation of the prior art in this field are the following U.S. Pat. Nos. 4,915,176; 5,420,370; 5,432,292; 5,723,524; 6,028,233; 6,093,863; 6,096,815 and 6,117,929; EPA 0526929A1; EPO 0323774A1; Can. Pat. Appln 2,073,577; WO 93/25798; WO 95/17579; Gas Hydrates and Hydrate Prevention 73 GPA Annual Convention, pgs 85-93; WO 96/08456; WO 96/08636; WO 93/25798; EPA 0457375A1 and WO 9412761.
SUMMARY OF THE INVENTION
What is described herein is a useful composition for effectively preventing or retarding the formation of gas hydrates, or for reducing the tendency of gas hydrates to agglomerate, during the transport of a fluid comprising water and a hydrocarbon, through a conduit, comprising an N-alkyl(meth)acrylamide homopolymer, N,N-dialkyl(meth)acrylamide homopolymer, or copolymers thereof with N-vinyl-N-methylacetamide, preferably with a suitable solvent. The homopolymer or copolymer is made and applied in a low molecular weight glycol ether, which, most preferably, is 2-butoxyethanol (BGE).
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Bakeev Kirill N.
Shih Jenn S.
Thieu Vu
Davis William J.
ISP Investments Inc.
Katz Walter
Maue Marilyn J.
Reddick Judy M.
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