Method for preparing transition metal complexes, transition...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

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C502S167000, C502S154000

Reexamination Certificate

active

07932207

ABSTRACT:
The present invention provides a novel transition metal complex where a monocyclopentadienyl ligand to which an amido group is introduced is coordinated, a method for synthesizing the complex, and olefin polymerization using the same. The method for preparing a transition metal complex according to the present invention comprises a step of blocking a by-reaction of a nitrogen atom using a compound containing a protecting group, and thus it is possible to prepare a transition metal complex in a simpler manner in a high yield. Further, the transition metal complex according to the present invention has a pentagon ring structure having an amido group connected by a phenylene bridge in which a stable bond is formed in the vicinity of a metal site, and thus, sterically monomers can easily approach the transition metal complex.

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patent: 2003/0065203 (2003-04-01), Wilson et al.
Enders et al., Journal of Organometallic Chemistry 549 (1997) 251-256.
M. Enders, et al. Organometallics, 2004, 23, 3832-3839.
Cho et al., Organometallics, 2006, 25, 2133-2134.
Joung et al., Organometallics, 2006, 25, 5122-5130.

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