Method for preparing thermoluminescent materials utilizing rare

Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides

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C09K 1146

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active

041168658

ABSTRACT:
Thermoluminescent materials have been found suitable for measuring long term exposures to low level ionizing radiation. Oxyhalides of lanthanum, gadolinium and yttrium, including the oxychlorides and oxybromides are activated with terbium and have been found to be most efficient oxygen dominated phosphors having thermoradiant efficiencies with excitation by low level ionizing radiation. Thermoluminescence response increases when the previous materials have elemental hafnium and zirconium additives. The thermoluminescent oxyhalide of the invention is prepared by forming mixed oxalates of the metal constituents, firing the mixed oxalates in air to form an oxide mixture, blending the oxide mixture with an ammonium halide and firing the resultant mixture to form the oxyhalide.

REFERENCES:
patent: 3591516 (1971-07-01), Rabatin
patent: 3617743 (1971-11-01), Rabatin et al.
patent: 3666676 (1972-05-01), Rabatin et al.

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