Method for preparing straight chain primary alcohols from 1-brom

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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560236, C07C 2900

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active

041172515

ABSTRACT:
Straight-chain, primary alcohols are prepared by reacting straight-chain 1-bromoalkanes having 6 to 20 carbon atoms with alkali salts of monocarboxylic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of monocarboxylic acids or alcohols based upon the alkali salt of the carboxylic acid and at temperatures ranging from 150.degree. to 300.degree. C. The esters formed are saponified in alkaline medium to the straight-chain, primary alcohols and separated.

REFERENCES:
patent: 1459971 (1923-06-01), Carter et al.
patent: 3655701 (1972-04-01), Darre
patent: 3968177 (1976-07-01), Kaufhold et al.

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