Method for preparing straight-chain primary alcohols

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2604109N, 260493, 260652P, 260660, C07C 2900

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active

039681777

ABSTRACT:
Straight-chain, primary alcohols are prepared by reacting straight-chain 1-chloroalkanes having 6 to 20 carbon atoms with alkali salts of monocarboxylic acids having 4 to 22 carbon atoms in the presence of 1 to 10 mole percent of monocarboxylic acids or alcohols based upon the alkali salt of the carboxylic acid and at temperatures ranging from 150.degree. to 300.degree.C. The esters formed are saponified in alkaline medium to the straight-chain, primary alcohols and separated.

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