Method for preparing single crystal oxide thin film

Single-crystal – oriented-crystal – and epitaxy growth processes; – Forming from vapor or gaseous state – With decomposition of a precursor

Reexamination Certificate

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Details

C117S084000, C117S085000, C117S092000

Reexamination Certificate

active

06929695

ABSTRACT:
The present invention is an tri-phase epitaxy method for preparing a single crystal oxide thin film, comprising the steps of depositing on a substrate an oxide thin film serving as a seed layer and having the same composition as that of an oxide thin film to be formed, depositing on the seed layer a thin film comprising a substance capable of being melted and liquidized by heat from the substrate and dissolving the oxide to be subsequent by deposited onto the seed layer, heating the substrate to form a liquid layer, and depositing an oxide on the seed layer through the liquid layer by use of a vapor-phase epitaxy method to form the single crystal oxide thin film. In this method, the oxygen partial pressure on the liquid layer is set in the range of 1.0 to 760 Torr during the film-forming step.

REFERENCES:
patent: 5885939 (1999-03-01), Matsunaga et al.
patent: 2-175613 (1990-07-01), None
patent: 7-101796 (1995-04-01), None
M. Kawasaki et al.,Tri-Phase Epitaxy For Single Crystalline Superconducting Thin Films, The Third Symposium on Atomic-Scale Surface and Interface Dynamics, Mar. 1999, (Discussed in p. 1 of the specification.).
B.D. Choi et al.,A New Concept of Epitaxy; Triple Phase Epitaxy(2p-X-4), The 58thJapan Society of Applied Physics Academic Lecture Drafts, Oct. 1997.
B.D. Choi et al.,Growth of the High Tc Superconducting ReBa2Cu3O7-xFilms by Triple Phase Epitaxy(2p-X-6), The 58thJapan Society of Applied Physics Academic Lecture Drafts, Oct. 1997.
B.D. Choi et al.,Optimization of the Conditions to Fabricate Re123 Thin Films by Tri-Phase Epitaxy(30a-SL-15), Mar. 1998.
B.D. Choi et al.,Liquid Film Composition Effects on the Property of Nd1+xBa2−xCu3O7−yThin Films by Tri-Phase Epitaxy, Fall 1998.
K.S. Yun et al.,Tri-Phase Epitaxy of High-Tc RBa2Cu3O7−xSuperconducting Thin Films, Chem—HTSC IV, Nov. 13, 1998.
M. Kawasaki et al.,Tri-Phase Epitaxy as a Novel Concept for Superconducting Films, MRS 1998 Fall Meeting, Symposium Q, Nov. 30-Dec. 3, 1998.
K.S. Yun et al.,Estimation of Nd1+xBa2−xCu3O7−yThin Films by Tri-Phase Epitaxy, Spring 1999.
M. Kawasaki et al.,Triphase Epitaxy of Single Crystalline High Tc Thin Films, The 1999 International Workshop on Superconductivity Co-sponsored by ISTEC and MRS, Jun. 27-30, 1999.

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