Method for preparing polyphenylene ethers

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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C08G 6544

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active

040922944

ABSTRACT:
A novel process is disclosed for the preparation of polyphenylene ethers by an oxidative coupling reaction. The process comprises oxidatively coupling a phenolic compound in the presence of a catalyst which comprises a copper complex of a copper compound with an N,N.sup.1 -disubstituted alkylene or cycloalkylene diamine having from 2 to 3 carbon atoms between the nitrogen atoms and whose substituents on the two nitrogens atoms are isopropyl or alpha tertiary alkyl, a tertiary amine, a secondary mono-amine and a bromine containing compound.

REFERENCES:
patent: 3733299 (1973-05-01), Cooper et al.
patent: 3787361 (1974-01-01), Nakashio et al.
patent: 3900445 (1975-08-01), Cooper et al.
patent: 3914266 (1975-10-01), Hay
patent: 3988297 (1976-10-01), Bennett et al.

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