Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing
Patent
1999-11-23
2000-11-14
Shaver, Paul F.
Organic compounds -- part of the class 532-570 series
Organic compounds
Silicon containing
C07F 708
Patent
active
061472433
ABSTRACT:
A method for preparing organosilicon compounds comprises: 1) converting the Si-bonded alkoxy in an Si-bonded alkoxy-functional organosilicon compound to the diorganosilyl group by reacting the Si-bonded alkoxy-functional organosilicon compound with organodisiloxane with the general formula HR.sub.2 Si--O--SiR.sub.2 H, where R is a monovalent hydrocarbyl group of 1 to 10 carbon atoms, in alcohol-containing acidic aqueous solution; and subsequently 2) treating with a sulfonic acid catalyst and carboxylic acid. This method is able to convert all the alkoxy groups in the alkoxy-functional organosilicon compound to diorganosilyl. This method can be used to synthesize a high-purity carbosiloxane dendrimer having a narrow molecular weight distribution.
REFERENCES:
patent: 5097054 (1992-03-01), Yamamoto et al.
patent: 5493040 (1996-02-01), Cobb et al.
Onodera Satoshi
Yoshitake Makoto
Dow Corning Toray Silicone Co. Ltd.
McKellar Robert L.
Shaver Paul F.
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