Method for preparing organic esters from halocarbons and alkali

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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C07C 67035

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active

050684019

ABSTRACT:
Organic esters such as propylene glycol diacetate are prepared in a single organic reaction phase from the corresponding halocarbon having from 3 to 8 carbon atoms, e.g., 1,2-dicholorpropane and the alkali or alkaline earth metal salt of a carboxylic acid. The inorganic salt formed thereby is not soluble in the organic phase. The reaction rate and selectivity are surprisingly good when the reaction contains little or no water.

REFERENCES:
patent: 3418360 (1968-12-01), Schulz et al.
patent: 3655701 (1972-04-01), Darre
patent: 3968177 (1976-07-01), Kaufhold et al.

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