Chemistry of hydrocarbon compounds – Adding hydrogen to unsaturated bond of hydrocarbon – i.e.,... – Using transition metal-containing catalyst
Patent
1988-06-30
1990-01-02
Davis, Curtis R.
Chemistry of hydrocarbon compounds
Adding hydrogen to unsaturated bond of hydrocarbon, i.e.,...
Using transition metal-containing catalyst
585271, C07C 502, C07C 505
Patent
active
048914568
ABSTRACT:
A method for preparing a norbornene structure compound comprises hydrogenating a compound represented by the formula of ##STR1## wherein l, m and n are integers of 0.ltoreq.l.ltoreq.3, 0.ltoreq.m.ltoreq.8 and 1.ltoreq.n.ltoreq.3, respectively, and each of R.sup.1 to R.sup.6 is a hydrogen atom or a hydrocarbon residue having 1 to 3 carbon atoms with or without R.sup.6 forming a ring with R.sup.4 or R.sup.5, in the presence of a Ziegler type catalyst containing in combination a compound of a transition metal of Groups IV to VI of the periodic table and an organometallic compound of Groups I to III of the periodic table, to thereby convert the compound of the formula (1) into a compound represented by the following formula of ##STR2## wherein l, m and n are the same as above.
REFERENCES:
patent: 4271323 (1981-06-01), Durand et al.
patent: 4675459 (1987-06-01), Yuasa et al.
Matsuno Mitsuo
Satoh Tetsuo
Yuasa Hitoshi
Davis Curtis R.
Nippon Oil Co. Ltd.
Wittenberg Malcolm B.
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